(I'm updating this just incase someone who has the same issue runs across this thread....in other words, in hopes that the Google search goes away)
Ok. I've re-flashed the DuoX2 Lite with the 5032 BIOS edited with XB2OOL to make F: 137, and G: gets the rest.
I then formatted the drive with A.I.D. 2.11 Final.
I then ran XBPartitioner, added a G: and made it 8gb.
From there I did the rest of the install as normal, but rather than doing a native install for GentooX, I did a F: install. This left my G: as is, but it also limited my max character length of my file names.
So long story short....you either get normal file names, no space for anything else, or you have to edit all your filenames, and have room for ripping games.