Hmmm... you seem to have gone wrong here. For example, what is that folder you have in there? That shouldn't be there. Also, don't put anything on E:\TDATA... put the Surreal.ini file back with the rest of the files. The emulator may make a copy of the ini file on E:, but it will do that on its own, you don't need to put it there yourself.
Just delete everything and start over from where you have your original compressed emulator package.
OK, so what dashboard are you using? If you want to place the emulator in E:\Emulators\ then you need to make sure the dashboard knows to look there for applications. Also, don't dump everything into Emulators folder, each emulator needs to be in its own sub folder... like this:
E:\Emulators\Surreal\*emulator files go here*
So just unzip/unrar the emulator and dump all the files where I showed above. You can call the folder inside the Emulators folder anything you want... Surreal, N64, whatever. The default.xbe file is the file that the XBox launches when you start Surreal (or pretty much any XBox app). So if you put everything on there correctly it should be located here:
E:\Emulators\Surreal\default.xbe
Now, if your dashboard is already set-up to find apps in E:\Emulators\ then Surreal should appear in your Emulators\Games\Apps... or whatever menu(s) your dashboard is set-up to use. If it's not in any of your application menus then we can fix that, but we need to know what dashboard you are using.