Welcome.
I don't have any real info compiled on it, and I'd imagine, if there already isn't, for there to be more than one board version of the thing, in true Sony fashion.
I've only ever had one to mess with here, and added back in several of the 'missing' buttons to it, and it's not really easy. The Nav controller is pretty much just crippled a DualShock 3. It has the same MCU, so the leads followed the same pinout as every controller in that respect, but as to every function being there or not I'm not sure. I do know that on the one I worked on I was able to add back in the R3, [ ], /\, R1 and R2 buttons.
There are no easy TP spots for doing anything so it would be all Vias or soldering to the MCU depending on what you're wanting to do. They're pretty cramped in there also, but I didn't keep any real track of the one I worked on as it was all soldering to the MCU leads.
If I run across another one I'll post up some scans and info on it, but it's not a controller that I've had any kind of requests for working on, so I haven't done much with them, except for that one, so far.