My favorite part of my nintendo is the paint...it's so flawless...but yes, it did turn out nicely.
And as far as I can tell, i'm the only person in the world to put a front window and relocate the Power button

But yeah, just paint over the NES logo.
I used fiberglass, and it's mounted underneath.
As for multimeters, you can pick them up at radioshack for pretty cheap. Lots and lots of tutorials about how to use them...Once you have one, I can't imagine being without it...it's such a vital part of any modder's toolbox.
The two features I use the most...touch one probe to ground and one to a power source, and it tells you how many volts...very useful.
The other one - Touch probes to two points and the multimeter will tell you if they're touching. Whenever I install LED's, I always make sure they're not shorting anywhere...it's saved me a number of times!!!
Anyways, Yes, I can tell you where to connect the LED's to! I can draw a paint diagram if this doesn't help...and it might not be right, but it's very close.
Do you see the last picture you posted? Underneath the largest capacitor, there's 5 solder joints in a vertical row.
The shielding and the top point are GROUND.
The second point is 3v?
The third point is 7v?
The fourth point is 12v
The fifth point is 12v
One of the 12v is always on, one is only on when the system is on. If I had to guess, I would say the 4th is switched, and the 5th is always on.
If you had a multimeter, you would turn the system on, put the black probe on ground, and touch each of those points with the positive end, and it would tell you EXACTLY the voltage it's putting out.
10 LED's is going to be tight...those PSU's don't have alot of juice in them. I put 4 in mine, and each one I added dimmed the chain a little more

Thinking back, though, I didn't wire the resistors right, so I'll go back someday and fix it...