Well you can, but you have to edit your INI. This is how mine looks for example:
Section "Games"
{
Item "Big Mutha Truckers","F:GamesBig Mutha Truckersdefault.xbe"
Item "Brute Force","F:GamesBrute Forcedefault.xbe"
Item "Burnout 2","F:GamesBurnout 2default.xbe"
Item "Crazy Taxi 3","F:GamesCrazy Taxi 3default.xbe"
Item "Enter the Matrix","F:GamesEnter the Matrixdefault.xbe"
Item "Finding Nemo","F:GamesFinding Nemodefault.xbe"
Item "Inside Pitch 2003","F:GamesInside Pitch 2003default.xbe"
Item "Largo Winch","F:GamesLargo Winchdefault.xbe"
Item "Metal Gear Solid 2: Substance","F:GamesMetal Gear Solid 2 Substancedefault.xbe"
Item "Micromachines","F:GamesMicromachinesdefault.xbe"
Item "Midnight Club 2","F:GamesMidnight Club 2default.xbe"
Item "Midtown Madness 3","F:GamesMidtown Madness 3default.xbe"
Item "Morrowind","F:GamesMorrowinddefault.xbe"
Item "MotoGP 2","F:GamesMotoGP 2default.xbe"
Item "Nascar Thunder 2003","F:GamesNascar Thunder 2003default.xbe"
Item "NBA Street Volume 2","F:GamesNBA Street Volume 2default.xbe"
Item "N.U.D.E.","F:GamesN.U.D.E.default.xbe"
Item "Return to Castle Wolfenstein: Tides of War","F:GamesReturn to Castle Wolfensteindefault.xbe"
Item "Rollercoaster Tycoon","F:GamesRollercoaster Tycoondefault.xbe"
Item "Soul Calibur 2","F:GamesSoul Calibur 2default.xbe"
Item "The Clone Wars","F:GamesThe Clone Warsdefault.xbe"
Item "The Sims","F:GamesThe Simsdefault.xbe"
Item "The Wild Rings","F:GamesThe Wild Ringsdefault.xbe"
}